Spectroscopic Techniques and Hindered Molecular Motion - Ferid Bashirov - Livros - Taylor & Francis Ltd - 9780367382285 - 19 de setembro de 2019
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Ferid Bashirov
Spectroscopic Techniques and Hindered Molecular Motion 1º edição

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Spectroscopic Techniques and Hindered Molecular Motion presents a united, theoretical approach to studying classical local thermal motion of small molecules and molecular fragments in crystals by spectroscopic techniques. Mono- and polycrystalline case studies demonstrate performance validity.





The book focuses on small molecules and molecular fragments, such as N2, HCl, CO2, CH4, H2O, NH4, BeF4, NH3, CH2, CH3, C6H6, SF6, and other symmetrical atomic formations, which exhibit local hindered motion in molecular condensed media: molecular and ionic crystals, molecular liquids, liquid crystals, polymeric solids, and biological objects. It reviews the state of studying the hindered molecular motion (HMM) phenomenon and the experimental works on the basis of the latest theoretical research.





Case Studies







Physical models of hindered molecular motion



General solution of the stochastic problem for the hindered molecular motion in crystals

Formulae of the angular autocorrelation function symmetrized on the crystallographic point symmetry groups

Formulae of the spectral line shapes concerning the dielectric, infrared, Raman, nuclear magnetic relaxation, and neutron scattering spectroscopy in the presence of the hindered molecular motion

Experimental probation of the theoretical outcomes

Proton relaxation in three-atomic molecular fragments undergoing axial symmetry hindered motion

Structural distortion in the ordered phase of crystalline ammonium chloride





Organic compounds, polymers, pharmaceutical products, and biological systems consist of the molecular fragments, which possess rotational or conformational degrees of freedom or an atomic exchange within the fragme

161 pages

Mídia Livros     Paperback Book   (Livro de capa flexível e brochura)
Lançado 19 de setembro de 2019
ISBN13 9780367382285
Editoras Taylor & Francis Ltd
Páginas 164
Dimensões 150 × 220 × 10 mm   ·   453 g
Idioma Inglês  

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